Growth of Pbsnanocompounds from Bis-(3-Phenyldithiocarbazato) Lead(II) Complex
Authors
-
Department of Chemistry, Midnapore College (Autonomous), Midnapore 721101 ,IN
Nilkamal Maiti
DOI:
https://doi.org/10.24906/isc/2018/v32/i2/173566Keywords:
Lead(II) Complex, Thermal Decomposition, Nanocompounds, UV-Vis Absorption, FL Spectroscopy.Abstract
The lead based complex with potassium 3-phenyldithiocarbazate, bis-(3-phenyldithiocarbazato) lead(II), was used for the preparation of nanosizedPbS compounds. The complex was thermally decomposed in ethylene glycol without using any surfactants or additivesunder soft reaction condition to prepare PbS nanocompounds. The products have been verifiedby transmission electron microscopy (TEM) and absorption spectroscopy. The diffused diffraction rings of the SAED pattern are the confirmation of prepared nanosized particles. TEM image shows the particles are irregular in nature and non-spherical shaped. UV-Vis optical spectroscopic study was carried out to determine the band gap energy of the nanocrystalline PbScompound and it is found to be 1.08eV.Downloads
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P. C. Ray, Size and Shape Dependent Second Order Nonlinear Optical Properties of Nanomaterials and Their Application in Biological and Chemical Sensing, Chem. Rev., Vol. 110, page 5332, 2010.
(a) F. J. Fan, L. Wu and S. H. Yu, Energetic I–III–VI2 and I2–II–IV–VI4 nanocrystals: preparation, photovoltaic and thermoelectric applications, Energy Environ. Sci., Vol 7, page 190, 2014 (b) M. Ibanez, R. Zamani, S. Gorsse, J. Fan, S. Ortega, D. Cadavid, J. R. Morante, J. Arbiol, and A. Cabot, Core–Shell Nanoparticles As Building Blocks for the Bottom-Up Production of Functional Nanos: PbTe–PbS Thermoelectric Properties, Nano, Vol 7, page 2573, 2013.
Z. Yang, C. Y. Chen, P. Roy and H. T. Chang, Quantum dot-sensitized solar cells incorporating nanomaterials, Chem. Commun., Vol 47, page 9561, 2011 (b) L. Yi, Y. Liu, N. Yang, Z. Tang, H. Zhao, G. Ma, Z. Su and D. Wang, One dimensional CuInS2–ZnS heterostructured nanomaterials as low-cost and high-performance counter electrodes of dye-sensitized solar cells, Energy Environ. Sci., vol 6, page 835, 2013.
E. Roduner, Nanoscopic Materials: Size-Dependent Phenomena. The Royal Society of Chemistry, Cambridge, 2006.
(a) V. I. RoldughinSelf-assembly of nanoparticles at interfacesRuss. Chem. Rev.,vol 73, page 115-145, 2004 (b) A. E. Sytschev and A. G. Merzhanov, Self-propagating high-temperature preparation of nanomaterials Russ. Chem. Rev., Vol 73, page 147, 2004.
Z. Zhang, Y. Liu, G. Yao, G. Zu, X. Zhang, J. Ma, Solid-state reaction preparation of NiFe2O4 nanoparticles by optimizing the synthetic conditionsPhysica E: Low-dimensional Systems and Nanostructures, Vol45, page 122-129, 2012(b) Z. Peng, A. Wang, C. L. Tian and J. S. Zheng, The recent developments and applications of the traceless-Staudinger reaction in chemical biology study, RSC Advances, Vol 130, Page 107192- 108066, 2015. (c)H. Karami,Preparation and Characterization of Iron Oxide Nanoparticles by Solid State Chemical Reaction Method, Journal of Cluster Science, vol 21, page 11-20, 2010.
Q.Xie, Z. Liu, M. Shao, L. Kong, W. Yu and Y. Qian,Polymer-controlled growth of Sb2Se3 nanoribbons via a hydrothermal process,Journal of crystal growth, Vol 252, page570,2003.
M. H. Chen and L. Gao, Polyol method preparation and characterization of nanoscale Sb2Se3 wires Res. Bull.Vol40, page 1120, 2005
Y.Yu, R. H. Wang, Q. Chen and L. M. Peng,Highquality ultralong Sb2Se3 and Sb2S3 nanoribbons on a large scale via a simple chemical route J. Phys. Chem. B, Vol 110, page 13415, 2006
J. Lu, Q. F. Han, X. J. Yang, L. D. Lu and X. WangPreparation of ultra-long Sb2Se3 nanoribbons via a short-time solvothermal process Mater. Lett. Vol 62,page2415, 2008.
H.Wang, J. J.Zhu, J. M. Zhu and H. Y. Chen, Sonochemical method for the preparation of bismuth sulfide nanorods J. Phys. Chem. B, Vol 106, page 3848, 2002
C.Zhao, X. Cao and X. Lan,Microwave-enhanced rapid and green preparation of well crystalline Sb2Se3 nanorods with a flat cross section Mater. Lett., Vol 61, page 5083, 2007
B.Zhou and J. J. Zhu,Microwave-assisted preparation of Sb2Se3 submicron rods, compared with those of Bi2Te3 and Sb2Te3 Nanotechnology, Vol20, page 85604, 2009
H. W. Chang, B. Sarkar and C. W. Liu,Preparation of Sb2Se3 nanowires via a solvothermal route from the single source precursor Sb[Se2P(OiPr)2]3, Cryst. Growth Des., Vol 7,page2691, 2007
N. Maiti, S. H. Im, Y. H. Lee, C. H. Kim and S. I. Seok, Solvent-assisted growth of Sb2Se3 nanomaterials from a single-source precursor under mild reaction conditions Cryst. Eng. Comm, Vol 13, page 3767, 2011
R. Romano, O. L. Alves, Semiconductor/porous silica glass nanos via the single-source precursor approach, Mater. Res. Bull. Vol 41, page 376, 2006.
(a) N. Maiti, S.H.Im, Y. H. Lee, and S. I. Seok,Urchinlike Nanostructure of Single-Crystalline Nanorods of Sb2S3 Formed at Mild Reaction Condition, ACS Appl. Mater. Interfaces, Vol 4, page 4787–4791, 2012(b) (b) N. Maiti, The Preparation and Characterization of bis(3-phenyldithio carbazato) lead(II): A New Single-source Precursor, Designed for Growth of PbS Nanocompounds, Advanced Journal of Basic & Applied Sciences, Vol 1, page 12, 2017.
G. Q. Xu, B. Liu, S. J. Xu , C. H. Chew and S. J. Brus, Luminescence studies of CdS spherical particles via hydrothermal preparation, Journal of Physics and Chemistry of Solids, Vol 61, page 829, 2000
(a) J. L. Pankove, Optical Process in Semiconductors, Dover Publications, New York, 1970 (b) K. K. Nanda, F. E. Kruis and H. Fissan, Band-gap tuning of PbS nanoparticles by in-flight sintering of size classified aerosols J. Appl. Phys., Vol. 91, page 15, 2002.
I. Kang and F. W. Wise,Electronic structure and optical properties of PbS and PbSe quantum dots,Journal of the Optical Society of America B,Vol14, page 1632, 1997
N. Chestnoy, T. D. Harris, R. Hull, L. E. Brus, Luminescence and photophysics of cadmium sulfide semiconductor clusters: the nature of the emitting electronic state, J. Phys. Chem., Vol 90, page 3393, 1986
