ZnO Polymer Nano Composites Synthesis, Characterization, and Thermo-Mechanical Property Comparison
DOI:
https://doi.org/10.18311/jmmf/2022/31218Keywords:
Polyester Resin, Polymer ZnO Nano Composites, Pure Polyester Sheet, Thermal, Mechanical Properties, Dielectric Spectroscopy, Hydrophobic Character.Abstract
Both the polyester resin matrix-based polymer ZnO nano composites and pure polyester sheet were synthesised using the solution casting method. The crystalline structure of the nano-particles was examined inside using X-ray diffraction (XRD). The fundamental polymer composition, additives, organic contaminants, and purity were all assessed by FTIR. A minor alteration in the absorption bands was seen in the polyester system with ZnO added. The thermal properties were examined using differential scanning calorimetry (DSC) and thermo gravimetric analysis (TGA), and the results unmistakably demonstrated the creation of a highly cross-linked polyester molecular structure or improved free volume fractions in polymer nano composites. A mechanical analyzer’s tensile and flexural strength tests revealed the potential for nanoparticle aggregation due to a strong interaction with resin. To calculate the relative permittivity and the loss of tangents (tan), dielectric studies had been used. Analysis of the hydrophobic properties of the pure and ZnO polyester nano composite.
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References
Ding Z, Wu L., Research development of weather-resistant epoxy resin. Technol. Dev. Chem. Ind. 2005; 34(1): 20–23.
Siddiqui RA, Abdullah HA., The effects of weathering on mechanical properties of glass fiber reinforced plastics (GRP) materials. ASME Pressure Vessels Piping Div.2000; 413: 63–68.
Segovia F, Ferrer C, Salvador MD, Amigo V., Influence of processing variables on mechanical characteristics of sunlight aged polyester-glass fibre composites. Polym. Degradation Stability 2000; 71(1): 179–184. DOI: https://doi.org/10.1016/S0141-3910(00)00168-3
Zhang M, Singh RP., Mechanical reinforcement of unsaturated polyester by Al2O3 nano-particles. Mater. Lett. 58(3-4) 2004; 408–412. DOI: https://doi.org/10.1016/S0167-577X(03)00512-3
Li Q, Chen S-L, Jiang W-C., Durability of nano ZnO anti-bacterial cotton fabric to sweat. J. Appl. Polym. Sci. 2007; 103(1): 412–416. DOI: https://doi.org/10.1002/app.24866
Li S, Toprak MS, Jo Y, Suk D, Jon K, Do K, Muhammed M., Bulk synthesis of transparent and homogeneous polymeric hybrid materials with ZnO quantum dots and PMMA. Adv. Mater. 2007; 19(24): 4347–4352. DOI: https://doi.org/10.1002/adma.200700736
Anand kumar Gupta, V.R., Balakrishnan, S.K. Tiwary., Synthesis of insitu generated ZnO incorporated PI high temperature resistive NC films: 72 FTIR, AFM, XRD, Micro hardness and Micromechanical study, International Journal of Polymer Technology, 2009; 1:181-188.
Merad, L., Benyousef, B., Abadie, M.J.M., Charles, J.P., Characterization and mechanical properties of epoxy resin reinforced with TiO2 nano-particles, Journal of Engineering and Applied Sciences, 2011; 6, 205-209. DOI: https://doi.org/10.3923/jeasci.2011.205.209
S.Yogeshwaran et al., “Experimental investigation on mechanical properties of Epoxy/graphene/fish scale and fermented spinach hybrid bio composite by hand lay-up technique.” Materials Today: Proceedings, vol. 37, no. 2, pp. 1578-1583, 2021. DOI: https://doi.org/10.1016/j.matpr.2020.07.160
Subramanian, Nagajothi, Elavenil Solaiyan, Angalaeswari Sendrayaperumal, and Natrayan Lakshmaiya. “Flexural behaviour of geopolymer concrete beams reinforced with BFRP and GFRP polymer composites.” Advances in Structural Engineering, 2022, pp. 1- 12. https://doi.org/10.1177/13694332211054229 DOI: https://doi.org/10.1177/13694332211054229
L. Natrayan, Anjibabu Merneedi, G. Bharathiraja, S. Kaliappan, Dhinakaran Veeman, P. Murugan, “Processing and Characterization of Carbon Nanofibre Composites for Automotive Applications”, Journal of Nanomaterials, vol. 2021, pp. 1-7, 2021. https://doi.org/10.1155/2021/7323885 DOI: https://doi.org/10.1155/2021/7323885
Dhinakaran Veeman, M. Varsha Shree, P. Sureshkumar, T. Jagadeesha, L. Natrayan, M. Ravichandran, Prabhu Paramasivam, “Sustainable Development of Carbon Nanocomposites: Synthesis and Classification for Environmental Remediation”, Journal of Nanomaterials, vol. 2021, pp. 1- 21, 2021. https://doi.org/10.1155/2021/5840645 DOI: https://doi.org/10.1155/2021/5840645
A. Bovas Herbert Bejaxhin, G.M. Balamurugan, S.M. Sivagami, K. Ramkumar, V. Vijayan and S. Rajkumar, “Tribological Behaviour and Analysis on Surface Roughness of CNC Milled Dual Heat Treated Al6061 Composites”, Advances in Materials Science and Engineering, Volume 2021, Article ID 3844194, 14 pages, https://doi.org/10.1155/2021/3844194 DOI: https://doi.org/10.1155/2021/3844194
J Jones Praveen, M Vinosh, A Bovas Herbert Bejaxhin, G Paulraj, “Embedded effect of ZrB2-Si3N4 on tribological behaviour of Al 8011 metal matrix composite”, Materials Today: Proceedings, Elsevier. https://doi.org/10.1016/j.matpr.2020.10.954. DOI: https://doi.org/10.1016/j.matpr.2020.10.954