Boronic Acid Functionalized Zirconium based MOF for the Complete Adsorptive Removal of Alizarin Dye

Jump To References Section

Authors

  • S. G. Prasannakumar
     Department of Chemistry, M.S. Ramaiah College of Arts, Science and Commerce, MSRIT Post, MSR Nagar, Bengaluru-560054, Karnataka ,IN
  • K. S. Asha
     Department of Chemistry, M.S. Ramaiah College of Arts, Science and Commerce, MSRIT Post, MSR Nagar, Bengaluru - 560054, Karnataka ,IN
  • S. P. Smrithi
     Department of Chemistry, M.S. Ramaiah College of Arts, Science and Commerce, MSRIT Post, MSR Nagar, Bengaluru - 560054, Karnataka ,IN

DOI:

https://doi.org/10.18311/jmmf/2023/43601

Keywords:

11B NMR, Metal-Organic Framework, Mixed-Ligand, Organic Pollutants, Solvothermal

Abstract

Nowadays, one of the severe problems that threaten the survival of human beings is water pollution. Water pollution caused by diverse poisonous compounds, specifically hydroxyl aromatic compounds and their derivatives have been evident and prominent environmental issue. In this work, an adsorptive method to remove the hydroxyl aromatic compounds particularly catechol based Alizarin red S dye by the activated metal organic framework have been attempted. The nano scale Zr-UiO-66 was synthesized using terephthalic acid as ligand, 4-carboxy phenyl boronic acid as coordination modulator and the morphology of the nano crystals was octahedral. The as-synthesized new metal organic framework Zr-UIO-66 after adsorption confirms the existence of boronic acid and structural stability after the incorporation of the boronic acid group using adsorption studies such as 11B NMR, PXRD, UV, IR and TGA. The zirconium based MOFs are very important in terms of their stability in water. These MOFs are largely used for gas separation, storage, sensing and degradation of chemical warfare agents, etc. The control of size of these MOFs to nano regime can be achieved using the monocarboxylic acids like acetic acid, benzoic acid. A mixed-ligand approach was implemented in this work.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

Downloads

Published

2024-05-24

How to Cite

S. G. Prasannakumar, Asha, K. S., & Smrithi, S. P. (2024). Boronic Acid Functionalized Zirconium based MOF for the Complete Adsorptive Removal of Alizarin Dye. Journal of Mines, Metals and Fuels, 71(12A), 404–409. https://doi.org/10.18311/jmmf/2023/43601

Issue

Volume 71, Issue 12A , 2023

Section

Articles

License

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

Crossref
Scopus
Google Scholar
Europe PMC

 

References

Smrithi SP, Kottam N, Narula A, Madhu GM, Riyaz M, Agilan R. Carbon dots decorated cadmium sulphide heterojunction- nanospheres for the enhanced visible light driven photocatalytic dye degradation and hydrogen generation. J. Colloid and Interface Sci. 2022; 627:956-68. https:// doi.org/10.1016/j.jcis.2022.07.100 PMid:35901574 DOI: https://doi.org/10.1016/j.jcis.2022.07.100

Smrithi SP, Kottam N, Vergis BR. Heteroatom-modified. Top. Catal. 2022; 1-12.

Devendra BK, Praveen BM, Tripathi VS, Nagaraju G, Nagaraju DH, Nayana KO. Highly corrosion resistant platinum- rhodium alloy coating and its photocatalytic activity. Inorg. Chem. Commun. 2021; 134:109065. https://doi. org/10.1016/j.inoche.2021.109065 DOI: https://doi.org/10.1016/j.inoche.2021.109065

Devendra BK, Praveen BM, Tripathi VS, Nagaraju G, Nayana KO, Nagaraju DH. Platinum coating on SS304: Photocatalytic dye degradation application. Iran. J. Sci. Technol. Trans A: Sci. 2022; 46:137-45. https://doi. org/10.1007/s40995-021-01250-w DOI: https://doi.org/10.1007/s40995-021-01250-w

Smrithi SP, Kottam N, Arpitha V, Archana N, Anilkumar GN, Subrahmanian KRV. Tungsten oxide modified with carbon nanodots: Integrating adsorptive and photocatalytic functionalities for water remediation, J. Sci.: Adv. Mater. Dev. 2020; 5(1):73-83. https://doi.org/10.1016/j.jsamd.2020.02.005 DOI: https://doi.org/10.1016/j.jsamd.2020.02.005

Devendra BM, Praveen BM, Tripathi VS, Nagaraju G, Prasanna BM, Shashank M. Development of rhodium coatings by electrodeposition for photocatalytic dye degradation. Vacuum. 2022; 205:111460. https://doi. org/10.1016/j.vacuum.2022.111460 DOI: https://doi.org/10.1016/j.vacuum.2022.111460

Liu Y, Cheng M, Liu Z, Zeng G, Zhong H, Chen M, Zhou C, Xiong W, Shao B, Song B. Heterogeneous Fenton-like catalyst for treatment of rhamnolipid-solubilized hexadecane wastewater. Chemosphere. 2019; 236:124387. https://doi. org/10.1016/j.chemosphere.2019.124387 PMid:31336240 DOI: https://doi.org/10.1016/j.chemosphere.2019.124387

Xiong W, Zeng Z, Li X, Zeng G, Xiao R, Yang Z, Zhou Y, Zhang C, Cheng M, Hu L. Multi-walled carbon nanotube/ amino-functionalized MIL-53 (Fe) composites: remarkable adsorptive removal of antibiotics from aqueous solutions. Chemosphere. 2018; 210:1061-9. https://doi.org/10.1016/j. chemosphere.2018.07.084 PMid:30208531 DOI: https://doi.org/10.1016/j.chemosphere.2018.07.084

Jiang D, Chen M, Wang H, Zeng G, Huang D, Cheng M, Liu Y, Xue W, Wang Z. The application of different typological and structural MOFs-based materials for the adsorption of the dye. Coord. Chem. Rev. 2019; 380:471-83. https://doi. org/10.1016/j.ccr.2018.11.002 DOI: https://doi.org/10.1016/j.ccr.2018.11.002

Fang Y, Wen J, Zeng G, Jia F, Zhang S, Peng Z, Zhang H. Effect of mineralizing agents on the adsorption performance of metal-organic framework MIL-100 (Fe) towards chromium (VI). Chem. Eng. J. 2018; 337:532-40. https:// doi.org/10.1016/j.cej.2017.12.136 DOI: https://doi.org/10.1016/j.cej.2017.12.136

Xiong W, Zeng G, Yang Z, Zhou Y, Zhang C, Cheng M, Liu Y, Hu L, Wan J, Zhou C. Adsorption of tetracycline antibiotics from aqueous solutions on nanocomposite multi-walled carbon nanotube functionalized MIL-53 (Fe) as new adsorbent. Sci. Total Environ. 2018; 627:235-44. https://doi. org/10.1016/j.scitotenv.2018.01.249 PMid:29426146 DOI: https://doi.org/10.1016/j.scitotenv.2018.01.249

Alvaro M, Carbonell E, Ferrer B, Llabres i Xamena FX, Garcia H. Semiconductor behaviour of a Metal-Organic Framework (MOF). Chemistry. 2007; 13:5106-12. https:// doi.org/10.1002/chem.200601003 PMid:17385196 DOI: https://doi.org/10.1002/chem.200601003

Nasalevich MA, Veen MVD, Kapteijn F, Gascon J. Metal– organic frameworks as heterogeneous photocatalysts: advantages and challenges. Cryst. Eng. Comm. 2014; 16:4919-26. https://doi.org/10.1039/C4CE00032C DOI: https://doi.org/10.1039/C4CE00032C

Li CX, Chen CB, Lu JY, Cuia S, Li J, Liu HQ, Li WW, Zhang F. Metal organic framework-derived CoMn2O4 catalyst for heterogeneous activation of peroxymonosulfate and sulfanilamide degradation. Chem. Eng. J. 2018; 337:101-9. https://doi.org/10.1016/j.cej.2017.12.069 DOI: https://doi.org/10.1016/j.cej.2017.12.069

Devendra BK, Praveen BM, Tripathi VS, Nagaraju DH, Nayana KO. Hydrogen evolution reaction by platinum coating. Iran. J. Sci. Technol. Trans. A: Sci. 2021; 45:1993- 2000. https://doi.org/10.1007/s40995-021-01220-2 DOI: https://doi.org/10.1007/s40995-021-01220-2

Smrithi SP, Kottam N, Muktha H, Mahule AM, Chamarti K, Vismaya V, Sharath R. Carbon dots derived from Beta vulgaris: evaluation of its potential as antioxidant and anticancer agent. Nanotechnology. 2021; 33:045403. https:// doi.org/10.1088/1361-6528/ac30f1 PMid:34666320 DOI: https://doi.org/10.1088/1361-6528/ac30f1

David U, Diaz E, S. Ordonez. Metal-Organic Frameworks (MOFs) as methane adsorbents: From storage to diluted coal mining streams concentration, Sci. Total Environ. 2021; 790:148211. https://doi.org/10.1016/j.scitotenv. 2021.148211 PMid:34111784 DOI: https://doi.org/10.1016/j.scitotenv.2021.148211

Liu H, Fu T, Mao Y. Metal–Organic Framework-Based materials for adsorption and detection of uranium(VI) from aqueous solution. ACS Omega. 2022; 7:14430-56. https://doi.org/10.1021/acsomega.2c00597 PMid:35557654 PMCid:PMC9089359 DOI: https://doi.org/10.1021/acsomega.2c00597

Gurushantha K, Kottam N, Smrithi SP, Dharmaprakash MS, Keshavamurthy K, Meena S, Srinatha N. Visible light active WO3/TiO2 heterojunction nanomaterials for electrochemical sensor, capacitance and photocatalytic applications. Cat. Lett. 2023; 1-12. https://doi.org/10.1007/s10562-023- 04362-7 DOI: https://doi.org/10.1007/s10562-023-04362-7