Dielectric Relaxation Studies on the Hydration Dynamics of Ionic, Non-Ionic and Zwitterionic Surfactants in Aqueous Acetate Buffer Solution

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Authors

  • R. Sampathkumar
     Department of Physics, Sathyabama Institute of Science and Technology, Chennai – 600119, Tamil Nadu ,IN
  • V. Balachandar
     Department of Physics, Sathyabama Institute of Science and Technology, Chennai – 600119, Tamil Nadu ,IN
  • D. Gopalakrishnan
     Department of Physics, Sathyabama Institute of Science and Technology, Chennai – 600119, Tamil Nadu ,IN

DOI:

https://doi.org/10.18311/jsst/2021/23899

Keywords:

Cole-Cole Plot, Complex Permittivity, Dielectric Relaxation, Hydration, Micelles, Surfactants, Time Domain Reflectometry, Thermodynamic Parameters

Abstract

Dielectric relaxation studies of acetate buffer solutions of Sodium Dodecyl Sulphate (SDS- anionic), Cetyl Trimethyl Ammonium Bromide (CTAB- cationic), Tween 80 (TW-80-non-ionic), Betaine Anhydrous (BA- zwitterionic) surfactants have been examined in the frequency region between 1GHz and 25GHz for various concentrations of surfactants at the temperatures of 283, 288, 293 and 298K using time domain dielectric spectroscopy. The obtained corrected loss spectra of all the amphiphiles except betaine anhydrous in acetate buffer solution depicted peaks near 1-2GHz and 15GHz, respectively. For betaine anhydrous, expected peak was not observed in the 1-2GHz frequency region. The peak ascertained near 15GHz, and another peak about 1-2GHz was accorded to free water relaxation and bound water reorientation of the surfactant micelles, and has acquired the reliance of temperature with concentration in detail. Single Debye and Cole-Cole function was employed to compute the relaxation times of free water and bound water, respectively. The Arrhenius plot was used to calculate the enthalpy and entropy for the micelle forming surfactants.

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Published

2023-02-15

How to Cite

Sampathkumar, R., Balachandar, V., & Gopalakrishnan, D. (2023). Dielectric Relaxation Studies on the Hydration Dynamics of Ionic, Non-Ionic and Zwitterionic Surfactants in Aqueous Acetate Buffer Solution. Journal of Surface Science and Technology, 37(3-4), 117–129. https://doi.org/10.18311/jsst/2021/23899

Issue

Volume 37, Issue 3-4, December 2021

Section

Articles
Crossref
Scopus
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Europe PMC
Received 2019-07-09
Accepted 2022-07-24
Published 2023-02-15

 

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